Spin gap in a quasi-one-dimensional antiferromagnet:
- 1 April 1998
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 57 (13) , 7846-7853
- https://doi.org/10.1103/physrevb.57.7846
Abstract
(1,4-diazacycloheptane) contains double chains of spin- ions. We report ac susceptibility, specific heat, and inelastic neutron-scattering measurements on this material. The magnetic susceptibility shows a rounded maximum at K indicative of a low-dimensional antiferromagnet with no zero-field magnetic phase transition. We compare the data with exact diagonalization results for various one-dimensional spin Hamiltonians and find excellent agreement for a spin ladder with intrarung coupling meV and two mutually frustrating interrung interactions meV and meV. The specific heat in zero field is exponentially activated with an activation energy meV. A spin gap is also found through inelastic neutron scattering on powder samples that identify a band of magnetic excitations for meV. Using sum rules we derive an expression for the dynamic spin-correlation function associated with noninteracting propagating triplets in a spin ladder. The Van Hove singularities of such a model are not observed in our scattering data, indicating that magnetic excitations in (1,4-diazacycloheptane) are more complicated. For magnetic fields above T specific-heat data versus temperature show anomalies indicating a phase transition to an ordered state below K.
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