Pyridylazonaphthols (PANs) and pyridylazophenols (PAPs) as analytical reagents. Part II. Spectrophotometric and solvent-extraction studies of complex formations
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in The Analyst
- Vol. 98 (1167) , 390-411
- https://doi.org/10.1039/an9739800390
Abstract
The reactions between 2-(2-pyridylazo)-1-naphthol (o-α-PAN), 1-(2-pyridylazo)-2-naphthol (o-β-PAN) and 2-(2-pyridylazo)phenol (o-PAP) with manganese(II), zinc(II) and lanthanum(III) and 4-(2-pyridylazo)phenol (p-PAP) with cobalt(II), nickel(II) and copper(II) have been studied. The spectrophotometric procedure based on linear extrapolation, as used by Sommer, has been critically evaluated. The results from the spectrophotometric method have been used to predict the optimum conditions for solvent extraction. It is shown that this procedure is a valuable approach for systems in which hydroxy-complexes are common.Keywords
This publication has 0 references indexed in Scilit: