A kinetic study of the pyrolysis of trimethylsilane
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 21,p. 1276-1277
- https://doi.org/10.1039/c29690001276
Abstract
Hydrogen and methane are formed in the pyrolysis of trimethylsilane by radical non-chain mechanisms, rate-determined by the dissociation of silicon-hydrogen and silicon–methyl bonds; radical disproportionations leading ultimately to cyclic products are important, but reactions forming silenes apparently are not.Keywords
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