THE RAMAN SPECTRUM OF THE SULPHURIC ACIDIUM ION: THE CONSTITUTION OF CONCENTRATED SOLUTIONS OF TETRA(HYDROGENSULPHATO)BORIC ACID IN SULPHURIC ACID
- 1 April 1962
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 40 (4) , 784-787
- https://doi.org/10.1139/v62-115
Abstract
The Raman spectra of sulphuric acid solutions of tetra(hydrogensulphato)boric acid and its sodium and hydronium salts have been examined. Frequencies are assigned to some of the vibrations of the sulphuric acidium ion, H3SO4+, and are compared with the frequencies of the analogous vibrations of H2SO4 and HSO4−. Evidence is presented that elimination of disulphuric acid occurs between molecules of HB(HSO4)4 to give polymers containing B—O—B linkages.Keywords
This publication has 2 references indexed in Scilit:
- THE RAMAN SPECTRA OF SULPHURIC, DEUTEROSULPHURIC, FLUOROSULPHURIC, CHLOROSULPHURIC, AND METHANESULPHONIC ACIDS AND THEIR ANIONSCanadian Journal of Chemistry, 1962
- THE RAMAN SPECTRA OF SOME POLYSULPHURYL CHLORIDES AND FLUORIDESCanadian Journal of Chemistry, 1961