Stereospecific Preparation of (E) and (Z)-3,3-Diarylacrylonitriles by Heck Reaction
- 1 October 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (10) , 1157-1158
- https://doi.org/10.1055/s-1997-988
Abstract
Both isomers 5 and 8 of 3,3-diarylacrylonitrile constitution are obtained in highly diastereoselective Pd-catalyzed Heck reactions under Jeffery conditions between (E)-cinnamonitriles and aryl iodides.Keywords
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