Diffuse scattering from oxide caused by Magneli-type plane defects
- 1 January 1990
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 64 (1) , 76-79
- https://doi.org/10.1103/physrevlett.64.76
Abstract
It is shown that if a periodical faulting of the double-period orthorhombic (1/200) phase in produces a Magneli series, , with a regular superlattice spots at [1/2+1/2(2n+1),0,0], the random faulting results in either broadening the (1/200) diffraction maximum or its splitting into two maxima, (1/2±ε,0,0), depending on the stoichiometry. The observation of these effects is a strong argument in favor of an assumption that this compound is inherently inhomogeneous due to the accommodation of nonstoichiometry by means of the formation of interstitial plane defects.
Keywords
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