Diffuse scattering from YBa2Cu3O7δ oxide caused by Magneli-type plane defects

Abstract
It is shown that if a periodical faulting of the double-period orthorhombic (1/200) phase in YBa2 Cu3 O7δ produces a Magneli series, YBa2 Cu3 O7(n/(2n+1), with a regular superlattice spots at [1/2+1/2(2n+1),0,0], the random faulting results in either broadening the (1/200) diffraction maximum or its splitting into two maxima, (1/2±ε,0,0), depending on the stoichiometry. The observation of these effects is a strong argument in favor of an assumption that this compound is inherently inhomogeneous due to the accommodation of nonstoichiometry by means of the formation of interstitial plane defects.