The Microwave Spectrum of C8H13Br and C8H13Cl
- 1 February 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (2) , 363-364
- https://doi.org/10.1063/1.1698886
Abstract
The spectrum and structure of the molecules C8H13Br and C8H13Cl have been determined. Despite the large size of these molecules, the spectra can be analyzed with the exception of the quadrupole hyperfine splittings which cannot be resolved. The B values are 1090.9 Mc for Cl35, 1065.9 for Cl37, 725.9 for Br79, and 718.5 for Br81. The value of the normal single bond carbon‐carbon distance is found to be dc—c=1.545±0.004A. The angle of twist about the symmetry axis is φ=0°±4°, and the angle between the carbon‐carbon and carbon‐halide bonds is θ=109°50′±10′.Keywords
This publication has 1 reference indexed in Scilit:
- Structure of the Methyl HalidesThe Journal of Chemical Physics, 1952