Spin isomerism in tris(monothio-β-diketonato)iron(III) complexes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1192-1195
- https://doi.org/10.1039/dt9720001192
Abstract
Mössbuer spectral parameters and paramagnetic susceptibilites have been measured for four tris(monothio-β-diketonato)iron(III) complexes. The results are interpreted in terms of a thermal equilibrium between sextet and doublet electronic states. In favourable case, superimposed spectra are observed in which both spin states can be recognised.Keywords
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