Gas Chromatographic Method for Analyzing C1-C5 Hydrocarbons

Abstract
A logarithmic plot of the relative retention times of C1–C5 hydrocarbon components taken from two different stationary liquid phases was used to predict the binary substrate composition required to separate thirty hydrocarbon component peaks. A fifty-fifty mixture of n-dodecane and 1-dodecene on a 0.01-in i.d. open tubular column produced thirty-one component peaks from a thirty-two component mixture in less than thirty minutes elution time.

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