Synthesis of zerovalent bis-(η-arene)(trimethylphosphine)-hafnium and -zirconium compounds using metal vapours

Abstract
Co-condensation of hafnium or zirconium atoms from an electron-gun furnace with arenes and trimethyl-phosphine gives good yields of the compounds [M(η-arene)2(PMe3)], M = Hf or Zr.

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