Model potentials and the optical spectra of solvated electrons
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 75, 1146-1158
- https://doi.org/10.1039/f29797501146
Abstract
Optical absorption spectra attributed to solvated electrons in ammonia, water, ethylenediamine and methanol are fitted by calculated photoejection spectra using a number of different model potentials. Theoretical spectra resulting from several spherically symmetric potentials yield excellent and in some cases indistinguishable representations of the experimental spectra. As a result, the optical spectra data are shown to provide only an insufficient basis for distinguishing between these different model potentials.Keywords
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