One-Pot Synthesis of 1-Alkynylphosphonates
- 1 September 1997
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 27 (18) , 3171-3174
- https://doi.org/10.1080/00397919708004175
Abstract
1-Alkynylphosphonates 3 are prepared in a one-pot procedure from diethyl phosphorochloridates 2 and alkynyllithiums 1, which are readily generated by the reaction of 1-alkynes with n-BuLi.Keywords
This publication has 4 references indexed in Scilit:
- Facile Synthesis of 1-AlkynylphosphonatesSynthetic Communications, 1996
- Nucleophilic substitution at acetylenic carbon. The last holdoutAccounts of Chemical Research, 1976
- Convenient synthesis of 1-alkynylphosphonatesThe Journal of Organic Chemistry, 1971
- Diels-Alder reaction in organometallic chemistry. V. Tetramethyl acetylenediphosphonate and dimethyl chloroacetylenephosphonate and their reactions with cyclopentadiene, 1,3-cyclohexadiene, and diazomethaneThe Journal of Organic Chemistry, 1969