Linear distortion of octahedral metal centres by multiple hydrogen bonds in modular ML4 systems
- 25 May 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 12,p. 1354-1355
- https://doi.org/10.1039/b402884h
Abstract
A series of compounds of the type [M(1)4(H2O)2]SO4·2H2O containing a simple urea-based pyridyl ligand have been synthesised and characterised by X-ray crystallography. The enclathrated water exists within discrete linearly stacked cavities and causes significant distortions in the M–OH2 bonds due to the presence of a strongly hydrogen bonded water square.Keywords
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