A high activity molybdenum containing epoxidation catalyst and its use in regioselective epoxidation of polybutadiene
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1688-1690
- https://doi.org/10.1039/c39890001688
Abstract
MoO2CI2[3-(diethoxyphosphinyl)camphor] is a highly active catalyst for the epoxidation of alkenes by ButOOH; for polybutadiene containing cis-1,4-trans-1,4-, and 1,2-polymerised units, very high selectivity to the backbone double bonds is observed.Keywords
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