Novel (1,3)-bifunctional organophosphorus(III) phosphonylating agents
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 13,p. 1369-1370
- https://doi.org/10.1039/p19930001369
Abstract
2-[Bis(trimethylsilyl)amido]-1,3.2-diazaphospholidine, [N,N′-(CH2NMe)2]P[N(SiMe3)2]1, has been synthesised from [N,N′-(CH2NMe)2]PCl and Li[N(SiMe3)2]. The activity of 1 as a phosphonylating agent is demonstrated by its ability to undergo the Abramov reaction with aldehydes.Keywords
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