Synthesis of allyltitanium compounds by intramolecular nucleophilic acyl substitution reaction of alka-3,5-dienyl carbonates and their unusual regioselectivity in reaction with aldehydes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 197-198
- https://doi.org/10.1039/cc9960000197
Abstract
Treatment of carbonates of alka-3,5-dien-1-ols with (η2-propene)Ti(OPri)2 resulted in intramolecular nucleophilic acyl substitution (INAS) reaction to afford allyltitanium compounds containing lactone or ester moieties, which add regiospecifically to aldehydes.Keywords
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