Ferro/antiferromagnetism mediated by interlayer organic spacers in layered copper(II) compounds
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1107-1108
- https://doi.org/10.1039/cc9960001107
Abstract
Spectacular and unexpected behaviours from long-range antiferromagnetic to ferromagnetic states are observed for a novel family of layered compounds, Cu2(OH)3X·mH2O (X =n-alkylcarboxylate) depending on the layer spacing (up to ca. 28 Å); in contrast, the analogous n-alkylsulfate derivatives are predominantly three-dimensional antiferromagnets.Keywords
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