Synthesis, fluxional behaviour, and oxidative-addition reactions of some µ-alkylthio-diplatinum(II) complexes
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 23,p. 2490-2494
- https://doi.org/10.1039/dt9760002490
Abstract
A series of complexes cis-[Pt2X2(PMe2Ph)2(µ-SMe)2](X = Cl, I, Me, or Ph) and cis-[Pt2X2(PMe2Ph)2(µ-SEt)2](X = Cl or Me) has been prepared. The complexes undergo a fluxional process thought to involve inversion at the bridging sulphur atoms. and the rate is strongly dependent on the group X. Reactions of the complexes with X = Me or Ph with methyl iodide are complicated and involve oxidative-addition–reductive-elimination sequences to give monomeric organoplatinum complexes as the final products.Keywords
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