Alkyl and Alkylidene Complexes of Tantalum That Contain a Triethylsilyl-Substituted Triamido−Amine Ligand
- 11 June 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (12) , 2777-2783
- https://doi.org/10.1021/om960149c
Abstract
No abstract availableKeywords
This publication has 21 references indexed in Scilit:
- Synthetic and Mechanistic Investigations of Trimethylsilyl-Substituted Triamidoamine Complexes of Tantalum That Contain Metal−Ligand Multiple BondsJournal of the American Chemical Society, 1996
- .alpha.-Elimination Can Be Faster than .beta.-Elimination in d2 Alkyl Complexes of Molybdenum and Tungsten That Contain the Trimethylsilyl-Substituted Triamidoamine LigandJournal of the American Chemical Society, 1995
- Synthesis of Molybdenum Complexes That Contain Silylated Triamidoamine Ligands. A .mu.-Dinitrogen Complex, Methyl and Acetylide Complexes, and Coupling of AcetylidesJournal of the American Chemical Society, 1994
- Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene ComplexJournal of the American Chemical Society, 1994
- Formation of Monomeric Terminal Chalcogenides by Template‐Induced Disilylchalcogenide Elimination; the Crystal Structures of [ETa{(Me3SiNCH2CH2)3N}] (E Se, Te)Angewandte Chemie International Edition in English, 1993
- Competitive .alpha.- and .beta.-elimination in an iridium alkylJournal of the American Chemical Society, 1988
- Convenient routes to vicinal diamines. Coupling of nitriles or N-(trimethylsilyl) imines promoted by NbCl4(THF)2Journal of the American Chemical Society, 1987
- Low-temperature neutron diffraction studies of carbon-hydrogen-metal interactions in two tantalum-neopentylidene complexes: [Ta(CHCMe3)(PMe3)Cl3]2 [T = 110 K] and the first alkylidene/olefin complex, Ta(.eta.5-C5Me5)(CHCMe3)(.eta.2-C2H4)(PMe3) [T = 20 K]Journal of the American Chemical Society, 1981
- Unprecedented regiospecificity and stereospecificity in reactions of Ph3C+PF6- with rhenium alkyls of the formula (.eta.-C5H5)Re(NO)(PPh3)(CH2R)Journal of the American Chemical Society, 1980
- Interaction of hydrogen and hydrocarbons with transition metals. Neutron diffraction evidence for an activated carbon-hydrogen bond in an electron-deficient tantalum-neopentylidene complexJournal of the American Chemical Society, 1979