Trapping of cyclopentadienone as a 4π component in Diels–Alder reactions with ethyl acrylate: a simple synthesis of (±)-sarkomycin
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1049-1050
- https://doi.org/10.1039/c39840001049
Abstract
The ability of cyclopentadienone to act as the diene counterpart in Diels–Alder reactions was demonstrated through the isolation of the cycloadduct with ethyl acrylate, which was utilized as the starting point for an expeditious synthesis of (±)-sarkomycin.Keywords
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