Protoadamantene as a synthetic precursor to 2,4-diaxial adamantane derivatives

Abstract
2,4-Diaxial-dibromoadamantane (V) and 2,4-diaxial-dihydroxyadamantane (VII) are obtained by bromination of protoadamantene (I) and by treatment of protoadamantene epoxide (VI) with aqueous acid, respectively.

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