Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin
- 8 July 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 31,p. 3906-3908
- https://doi.org/10.1039/b508135c
Abstract
A self-complementary tecton based on a zinc porphyrin core bearing two pyridines at the opposite meso positions leads to the formation of a 3-D coordination network in the crystalline phase which offers channels which are filled with solvent molecules; reversible exchange of the guest molecules has been proven to take place in a single-crystal-to-single-crystal type transformation demonstrating the robustness of the coordination framework.Keywords
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