A key intermediate in nickel-catalysed butadiene dimerisation; its identity in solution and in the solid state
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1240-1241
- https://doi.org/10.1039/c29710001240
Abstract
An i.r. spectroscopic study of 1-h1-6,7,8-h3-cis-2-trans-6-octadienediyltricyclohexylphosphinenickel(0) and its dodecadeuterio-analogue shows that this structure persists in solution and in the solid state, and provides no evidence for a rearrangement in the solid state to the bisbutadiene complex.Keywords
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