Some studies in inorganic complexes. XXIV. Copper(II) complexes of 2-acetamidopyridine and 2-methylpyridine-6-carboxylic acid
- 1 January 1969
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 22 (9) , 1835-1839
- https://doi.org/10.1071/ch9691835
Abstract
Complexes of copper(II) with 2-acetamidopyridine (acpy) and with 2- methyl-pyridine-6-carboxylic acid (mepiac-H) have been prepared. The compounds studied included [Cu(acpy)2Cl2], [Cu(acpy)2Br2], [Cu(acpy)2(NCS)2], [Cu(acpy)2(NO3)2], [Cu(acpy)2(H2O)ClO4]ClO4,H2O, [Cu(mepiac)(mepiac-H)Cl], [Cu(mepiac)(mepiac-H)-Br], [Cu(mepiac)(mepiac-H)BrH2O], and [Cu(mepiac)2H2O]. The magnetic properties, conductances, reflectance and solution spectra, as well as infrared spectra, are in agreement with the copper(II) complexes of acpy being six-coordinate and those of mepiac-H having a five- coordinate structure.Keywords
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