Pyromellitimide-bridged porphyrins as model photosynthetic systems. 1. Synthesis and steady state fluorescence properties
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 2435-2437
- https://doi.org/10.1039/p19850002435
Abstract
A two-step synthesis of pyromellitimide-bridged porphyrins is described. These compounds offer a convenient route to model photosynthetic systems of predetermined geometry. Very strong quenching of the fluorescence emission bands on irradiation at the Soret wavelength is suggestive of electron transfer interactions.This publication has 5 references indexed in Scilit:
- Coordination chemistry and geometries of some 4,4'-bipyridyl-capped porphyrins. Proton- and ligand-induced switching of conformationsJournal of the American Chemical Society, 1985
- Intramolecular Photochemical Electron Transfer. 1. EPR and Optical Absorption Evidence for Stabilized Charge Separation in Linked Porphyrin-Quinone MoleculesJournal of the American Chemical Society, 1983
- Quinone-capped porphyrins: n.m.r. studies of static and dynamic stereochemistry and co-ordination propertiesJournal of the Chemical Society, Perkin Transactions 1, 1982
- Quinone-capped porphyrins: synthesis and some chemical propertiesJournal of the Chemical Society, Perkin Transactions 1, 1982
- Syntheses of covalently‐linked porphyrin‐quinone complexesJournal of Heterocyclic Chemistry, 1980