The X-ray crystal; structure of trans-tri-iodobis(trimethylphosphine)manganese(III). The first example of a trigonal bipyramidal manganese(III) tertiary phosphine complex
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 658-659
- https://doi.org/10.1039/c39840000658
Abstract
The reaction of Mnl2(PMe3)with dioxygen leads to the formation of the trigonal bipyramidal bisphosphine manganese(III) complex, trans-Mnl3(PMe3)2; no phosphine oxidation is observed.Keywords
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