The selective conversion of n-pentane into pent-1-ene via trihydrido(trans-penta-1,3-diene)bis(triarylphosphine)rhenium
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 1235-1236
- https://doi.org/10.1039/c39820001235
Abstract
Treatment of n-pentane with heptahydridobis(triarylphosphine)rhenium and 3,3-dimethylbutene gives trihydrido(trans-penta-1,3-diene)bis(triarylphosphine)rhenium; trimethyl phosphite converts this, with high selectivity, into pent-1-ene.Keywords
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