One-Dimensional μ-Chloromanganese(II)−Tetrathiafulvalene (TTF) Coordination Compound
- 18 March 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (8) , 3152-3154
- https://doi.org/10.1021/ic060056f
Abstract
A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(μ-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.Keywords
This publication has 25 references indexed in Scilit:
- Magnetic Molecular ConductorsChemical Reviews, 2004
- Magnetic TTF-Based Charge-Transfer ComplexesChemical Reviews, 2004
- New Trends in the Synthesis of π-Electron Donors for Molecular Conductors and SuperconductorsChemical Reviews, 2004
- Organic Metals and Superconductors Based on BETS (BETS = Bis(ethylenedithio)tetraselenafulvalene)Chemical Reviews, 2004
- A Series of Redox Active, Tetrathiafulvalene‐Based Amidopyridines and Bipyridines Ligands: Syntheses, Crystal Structures, a Radical Cation Salt and Group 10 Transition‐Metal ComplexesChemistry – A European Journal, 2004
- Multiproperty Molecular Materials: TTF‐Based Conducting and Magnetic Molecular MaterialsEuropean Journal of Inorganic Chemistry, 2004
- TTF ChemistryPublished by Springer Nature ,2004
- Synthesis and characterization of TTF-type precursors for the construction of conducting and magnetic molecular materialsTetrahedron Letters, 2003
- Novel unsymmetrically functionalized BEDT–TTF derivatives: synthesis, crystal structure and electrochemical characterizationComptes Rendus. Chimie, 2003
- Facile Synthesis of Novel Functionalized Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) DerivativesThe Journal of Organic Chemistry, 2002