Kristallstruktur von 2‐Lithio‐2‐methyl‐1,3‐dithian‐Tetramethylethylendiamin (1/1)
- 20 January 1980
- journal article
- Published by Wiley in Angewandte Chemie
- Vol. 92 (1) , 59-60
- https://doi.org/10.1002/ange.19800920121
Abstract
Überraschende Strukturmerkmale enthüllte die röntgenographische Untersuchung der Titelverbindung (1): Sie kristallisiert als Dimer, und je ein Molekül des Solvens TMEDA (Tetramethylethylendiamin) ist spiranartig an ein Li‐Atom koordiniert. Die äquatoriale Position des Lithiums wird also vielleicht durch sterische und nicht durch elektronische Faktoren bewirkt. magnified imageKeywords
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