Structural chemistries and X-ray crystal structures of some macrocyclic tertiary phosphine complexes of d 8 metal ions: [IrCl(CO){Bu2 tP(CH2)10PBu2 t}], [PtCl2{Bu2 tP(CH2)12PBu2 t}], and [RhCl(CO){Bu2 tP(CH2)10PBu2 t}]2
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 584-585
- https://doi.org/10.1039/c39750000584
Abstract
The structural characterization of [IrCl(CO){Bu2 tP(CH2)10PBu2 t}], [PtCl2{Bu2 tP(CH2)12PBu2 t}], and [RhCl(CO){Bu2 tP(CH2)10PBu2 t}]2 are summarized with emphasis on the observed conformations of the macrocycles and prefered stereochemistries at the metal.Keywords
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