Dimeres Nitrosobenzol-eisentricarbonyl durch strahlenchemische Umsetzung von Fe(CO)5 mit Nitrobenzol
Open Access
- 1 June 1965
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 20 (6) , 521-523
- https://doi.org/10.1515/znb-1965-0605
Abstract
The preparation of a new complex, dimeric nitrosobenzene-irontricarbonyl, by irradiation of Fe(CO)5 in nitrobenzene with light or 60Co-γ-rays is described. According to IR-spectroscopic data nitrosobenzene molecules are the only bridging ligands in this complex. The mechanism of the reduction of nitrobenzene to nitrosobenzene is discussed.Keywords
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