Generalized Universal Molecular Weight Calibration Parameter in GPC

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Abstract
In this report we show by experimental and theoretical investigations that the commonly used GPC universal calibration parameter, the intrinsic viscosity multiplied by the weight average molecular weight ([η] Mw) is incorrect. The error which can arise by using [η] M to calculate the molecular weight across the GPC chromatogram for nonuniformly branched polymers [poly(vinyl acetate) and low density polyethylene] and copolymers with compositional drift, could be very large. We also show conclusively that the number average molecular weight Mn is the correct average to use for the universal calibration parameter. We therefore recommend that our general universal Calibration parameter [η] Mn be used for calculating the molecular weight across the chromatogram for all polymer systems (linear and branched homopolymers, copolymers with or without compositional drift and for polymer blends).