Stable oxo-iron(IV) porphyrin ? radical cation related to the oxidation cycles of cytochrome P-450 and peroxidase
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 716-717
- https://doi.org/10.1039/c39910000716
Abstract
A porphyrin having twelve phenyl groups was synthesized and the stable oxo-iron(IV) porphyrin π radical cation at 8 °C was formed by the reaction of this porphyrin iron(III) complex and m-chloroperbenzoic acid.Keywords
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