Abstract
The new compounds Sr2Bi, Ba2Sb, Sr5Bi3, Ba5Sb3 and Ba5Bi3 were prepared and their structures determined. The A2B-compounds crystallize tetragonal bodycentered and are isotypic to Ca2Sb, Ca2Bi and Sr2Sb. The A5B3-compounds build up the Mn5Si3-structure type. In both structures the element (V) atoms are coordinated only to earth alkali atoms.

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