Novel perfluoroalkylation of alkenes with perfluoroalkanesulphonyl chlorides catalysed by a ruthenium(II) complex
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 3,p. 627-633
- https://doi.org/10.1039/p19910000627
Abstract
The perfluoroalkylation of acyclic and cyclic alkenes by perfluoroalkanesulphonyl chlorides 1 has been investigated in the presence of a ruthenium(II) catalyst. The addition reactions proceeded smoothly, with extrusion of sulphur dioxide, in alkenes possessing either an electron-donating or an electron-withdrawing group, at 120 °C to give the corresponding chloroperfluoroalkylated compounds in high yield.Keywords
This publication has 0 references indexed in Scilit: