Absorption spectra of dimer cations. Part 1.—Olefins
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 65, 2576-2581
- https://doi.org/10.1039/tf9696502576
Abstract
The absorption spectra of γ-irradiated glasses at 77 K containing cyclohexene, butadiene and penta-1,3-diene have been studied. The effects of warming and recooling and of concentration show that the bands can be assigned to monomeric and dimeric radical cations (M+ and M+ 2). Assignments of the corresponding spectra of a number of olefins obtained by other workers are discussed.Keywords
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