Abstract
The 13C nmr spectra of a series of 20 bicyclo[3.2.1]octanols and -octenols have been determined to examine the shielding effects of the hydroxyl group on the skeletal carbons in this ring system. For comparison, the previously unreported data for a few closely related alcohols in the [2.1.1], [2.2.1], and [3.2.2] systems were also collected. The utility of these substituent effects for configuraional and conformational assignments is discussed.

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