The viscosity of liquid mixtures
- 1 January 1981
- journal article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 34 (8) , 1573-1577
- https://doi.org/10.1071/ch9811573
Abstract
A semiempirical equation is proposed to describe the effect on the viscosity of a solvent due to the addition of a solute. This equation is applied to many types of mixtures but not those for which components are electrolytes or water. The B coefficient at infinite dilution is B°2 = V·1 + V·2 /2[ln�� η·2�/In η·1 - H°/2-H·2 / 2.45RT ] where H°2-H·2 is the heat of solution of the liquid solute, V·1 and V·2 the molar volumes and η·2 and η·1 the viscosities of the pure components.Keywords
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