Katalytische Synthese von Hydridmagnesiumchlorid aus Magnesium, Wasserstoff und Magnesiumchlorid/ Catalytic Synthesis of Hydridomagnesium Chloride from Magnesium, Hydrogen and Magnesium Chloride
Open Access
- 1 August 1984
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 39 (8) , 1001-1003
- https://doi.org/10.1515/znb-1984-0802
Abstract
THF solutions of hydridomagnesium chloride (HMgCl, 1a) can be prepared in nearly quantitative yields by hydrogenation of magnesium in THF solutions of magnesium chloride at 0 °C in the presence of a CrCl3-Mg anthracene catalyst. Concentration of saturated HMgCl solutions, or hydrogenation of magnesium under the above mentioned conditions in MgCl2-THF suspensions, lead to the formation of THF solutions of species having the approximate com position HMgCl · MgH2 or 2 HMgCl · MgH2.Keywords
This publication has 0 references indexed in Scilit: