The electron impact induced cleavage of the C-17—C-20 bond and D-ring in trimethylsilyl derivatives of C21 steroids. Reciprocal exchange of trimethylsilyl groups
- 1 May 1980
- journal article
- research article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 7 (5) , 217-225
- https://doi.org/10.1002/bms.1200070508
Abstract
No abstract availableKeywords
This publication has 25 references indexed in Scilit:
- Vinyldimethylsilyl ethers as derivatives for the characterization of steroids and cannabinoids by gas chromatography mass spectrometryJournal of Mass Spectrometry, 1980
- Silyl derivatives of steroids. Intramolecular silylation processes and electron impact-induced reciprocal exchange of trimethylsilyl groupsThe Journal of Organic Chemistry, 1973
- Method for selective introduction of trimethylsilyl and perdeuteriotrimethylsilyl groups in hydroxy steroids and its utility in mass spectrometric interpretationsAnalytical Chemistry, 1973
- Comparison of corticosteroid derivatives by gas chromatography-mass spectrometryAnalytical Chemistry, 1972
- The mass spectra of some corticosteroid boronatesJournal of Mass Spectrometry, 1971
- Oxygen-18 exchange reactions in steroidal ketones. Determination of relative rates of incorporation by gas chromatography-mass spectrometrySteroids, 1969
- Conversion of steroids to trimethylsilyl derivatives for gas phase analytical studies: Reactions of silylating reagentsAnalytical Biochemistry, 1969
- Steroids in Germfree and Conventional RatsEuropean Journal of Biochemistry, 1968
- Use of deuterium-labeled trimethylsilyl derivatives in mass spectrometryAnalytical Chemistry, 1968
- Identifiction of 3β, 17β-dihydroxyandrost-5-ene, 3β,20α-dihydroxypregn-5-ene and epiandrosterone in human peripheral bloodSteroids, 1966