Discrete and infinite coordination arrays derived from a template-directed, solid-state, organic synthesis
- 15 July 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 4 (41) , 223-226
- https://doi.org/10.1039/b202169b
Abstract
A product derived from a template-directed, organic, solid-state synthesis, rctt-tetrakis(2-pyridyl)cyclobutane (2,2′-tpcb), serves as a bis-chelating ligand upon reaction with Cu(NO3)2·2.5H2O and CuSO4·5H2O to produce discrete and infinite coordination arrays, [Cu2(NO3)4(μ-2,2′-tpcb)] (1) and [Cu2(μ2-SO4)2(μ-2,2′-tpcb)(H2O)2]n·9H2O (2), respectively.Keywords
This publication has 18 references indexed in Scilit:
- From engineering crystals to engineering molecules: emergent consequences of controlling reactivity in the solid state using linear templatesCrystEngComm, 2002
- Exploiting modularity in template-controlled synthesis: a new linear template to direct reactivity within discrete hydrogen-bonded molecular assemblies in the solid stateChemical Communications, 2001
- Latent chemical behavior revealed in the crystalline state: novel photochemistry of a cis-9-decalyl aryl ketoneChemical Communications, 2000
- Supramolecular Control of Reactivity in the Solid State Using Linear Molecular TemplatesJournal of the American Chemical Society, 2000
- Reactivity of organic solids — retrospect and prospectSolid State Ionics, 1997
- In situ ligand synthesis and construction of an unprecedented three-dimensional array with silver(i): a new approach to inorganic crystal engineeringChemical Communications, 1997
- Aromatic-aromatic interactions: free energy profiles for the benzene dimer in water, chloroform, and liquid benzeneJournal of the American Chemical Society, 1990
- Photochemical reactions of organic crystalsChemical Reviews, 1987
- Azastilbenes. 1. Synthesis, characterization, and structureThe Journal of Organic Chemistry, 1980
- Azastilbenes. 2. PhotodimerizationThe Journal of Organic Chemistry, 1980