Influence of Atomic Masses on the Coriolis Coupling Coefficients in some Symmetrical Molecules. Part III. Planar Symmetrical XY3 Molecules and Ions
Open Access
- 1 October 1964
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung A
- Vol. 19 (10) , 1148-1150
- https://doi.org/10.1515/zna-1964-1002
Abstract
CORIOLIS coupling coefficients for the planar symmetrical XY3 molecular model are studied. One has found the upper limits |ζ23| → and ζ3 →· 1 with increasing atomic mass ratio mY/mX. Lower limits are also given, and appear to be functions of the force constants. Calculated ζ23 and ζ3 values for sixteen molecules (and radicals), and five ions of the considered type are reported. Curves are given for the mass-ratio dependence.Keywords
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