Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n
- 12 December 2002
- journal article
- letter
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 27 (2) , 230-232
- https://doi.org/10.1039/b209564e
Abstract
A helical chain of [Co(1,10-phen)2(V2O4)(O3PCH2CH2CH2PO3)]n (1) and a stepped chain of [{Co(1,10-phen)2}2(V4O10)(O3PCH2CH2CH2CH2PO3)(2H2O)]n (2) have been synthesized under hydrothermal conditions using [Co(1,10-phen)2]2+ as the metal-organic subunit and organic diphosphonate ligands of different lengths.Keywords
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