Regiocontrolled lithiation of arenetricarbonylchromium (0) complexes: meta-substitution of phenols and anilines
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 955-956
- https://doi.org/10.1039/c39830000955
Abstract
Tri-isopropylsilyl ethers of phenol- and aniline-tricarbonylchromium(0) complexes are lithiated predominantly meta to the heteroatom and subsequent reaction with suitable electrophiles produces overall meta-electrophilic substitution of phenols and anilines.Keywords
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