Use of 13C-1H spin-coupling constants in the determination of side-chain conformations of amino-acids
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 465-466
- https://doi.org/10.1039/c39740000465
Abstract
It is shown that by considering the 13C–C–C–H coupling constant between the α-CO2 – and the β-protons in amino-acids it is possible to obtain side-chain conformational information concerning the rotamer populations which is not available from studies of H–H coupling constants alone.Keywords
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