COPPER (II) COORDINATION COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA
- 1 February 1997
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 41 (1-2) , 35-182
- https://doi.org/10.1080/00958979708027956
Abstract
This review summarizes the data for over twelve hundred four - and five - coordinate copper(II) coordination compounds. The four-coordinate derivatives are mostly distorted square-planar. The five-coordinate derivatives are mostly square-pyramidal. The most common ligands are oxygen- and nitrogen- donors. There is a trend for the Cu-L distance to increase with covalent radius of the coordinated atom and also increasing coordination number. There are three types of isomerism - distortion, cis- and trans- and configuration. Several relationships are found and discussed.Keywords
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