Fluctuation effects and multiscaling of the reaction-diffusion front for A+B to OE
- 7 July 1995
- journal article
- Published by IOP Publishing in Journal of Physics A: General Physics
- Vol. 28 (13) , 3599-3621
- https://doi.org/10.1088/0305-4470/28/13/007
Abstract
We consider the properties of the diffusion-controlled reaction A+B to OE in the steady state, where fixed currents of A and B particles are maintained at opposite edges of the system. Using renormalization-group methods, we explicitly calculate the asymptotic forms of the reaction front and particle densities as expansions in (JD-1 mod x mod d+1)-1, where J are the (equal) applied currents, and D the (equal) diffusion constants. For the asymptotic densities of the minority species, we find, in addition to the expected exponential decay, fluctuation-induced power-law tails, which, for d2, we find similar power laws with mu =d+3, but with non-universal coefficients. Logarithmic corrections occur in d=2. These results imply that, in the time-dependent case, with segregated initial conditions, the moments integral mod x mod qR(x,t) dx fail to satisfy simple scaling for q> mu +1. Finally, it is shown that the fluctuation-induced wandering of the position of the reaction front centre may be neglected for large enough systems.Keywords
All Related Versions
This publication has 26 references indexed in Scilit:
- Diffusion-reaction kinetics forA+B(static)→C(inert) for one-dimensional systems with initially separated reactantsPhysical Review A, 1992
- Reaction front forA+B→Cdiffusion-reaction systems with initially separated reactantsPhysical Review A, 1992
- Inhomogeneous two-species annihilation in the steady stateJournal of Physics A: General Physics, 1992
- ‘‘Random-force-dominated’’ reaction kinetics: Reactants moving under random forcesPhysical Review Letters, 1992
- Space-and time-resolved diffusion-limited binary reaction kinetics in capillaries: experimental observation of segregation, anomalous exponents, and depletion zoneJournal of Statistical Physics, 1991
- Some properties of the a+b ? C reaction-diffusion system with initially separated componentsJournal of Statistical Physics, 1991
- Role of fluctuations for inhomogeneous reaction-diffusion phenomenaPhysical Review A, 1991
- Microscopic Study of the Properties of the Reaction Front in an A + B → C Reaction-Diffusion ProcessEurophysics Letters, 1991
- Simulation study of reaction frontsPhysical Review A, 1990
- Properties of the reaction front in antype reaction-diffusion processPhysical Review A, 1988