Conformationally restricted Criegee intermediates: evidence for formation and stereoelectronically controlled fragmentation
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 10,p. 2141-2143
- https://doi.org/10.1039/p29940002141
Abstract
The Baeyer–Villiger reaction of 2-(2-oxocyclohexyl)acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the-but-2-yl ester and of 2-(2-oxocyclopentyl)acetic acid also show evidence of such stereoelectronic control, but less convincingly.Keywords
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