The photolysis of octaisopropylcyclotetrasilane; evidence for the formation of hexaisopropylcyclotrisilane and tetraisopropyldisilene
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 66-67
- https://doi.org/10.1039/c39840000066
Abstract
Irradiation of octaisopropylcyclotetrasilane (1) in a hydrocarbon solvent successively afforded hexaisopropylcyclotrisilane [Pri 2Si]3(2)(λmax320 nm) and tetraisopropyldisilene [Pri 2SiSiPri 2](3)(λmax 400 nm) with extrusion of di-isopropylsilanediyl (4).Keywords
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