Stereochemistry of solvolysis of halogenocarbene adducts of cyclic olefins
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 20,p. 1365-1366
- https://doi.org/10.1039/c29700001365
Abstract
The Ag+-assisted solvolysis of dibromo- and exo-monobromo-carbene adducts of cycloheptene and the dibromocarbene adduct of cyclo-octa-1,5-diene is stereospecific; methanolysis of 9,9-dibromobicyclo[6,1,0]-non-4-ene (5; X = Y = Br) occurs on the same side of the incipient allylic system as that of the leaving group.Keywords
This publication has 0 references indexed in Scilit: